Mellican, R.E., From fusion frenzy to fraud: Reflections on science and its cultural norms. Bull. Sci. Tech. Soc., 1992. 12: p. 1.
Coauthors:Mendes, R.V., Ergodic motion and near collisions in a Coulomb system. Mod. Phys. Lett. B, 1991. 5: p. 1179.
Coauthors:Mengoli, G., et al., The observation of tritium in the electrolysis of D2O at palladium sheet electrodes. J. Electroanal. Chem., 1991. 304: p. 279.
Coauthors: Fabrizio, M., Manduchi, C., Zannoni, G., Riccardi, L., Veronesi, F., Buffa, A.Mengoli, G., et al. Tritium and Neutron Emission in Conventional and Contact Glow Discharge Electrolysis of D2O at Pd and Ti Cathodes. in Second Annual Conference on Cold Fusion, "The Science of Cold Fusion". 1991. Como, Italy: Societa Italiana di Fisica, Bologna, Italy.
Coauthors: Fabrizio, M., Manduchi, C., Zannoni, G., Riccardi, L., Buffa, A.Mengoli, G., et al., Tritium and neutron emission in D2O electrolysis at Pd and Ti cathodes. J. Electroanal. Chem., 1992. 322: p. 107.
Coauthors: Fabrizio, M., Manduchi, C., Zannoni, G., Riccardi, L., Buffa, A.Mengoli, G., et al., Surface and bulk effects in the extraction of hydrogen from highly loaded Pd sheet electrodes. J. Electroanal. Chem., 1993. 350: p. 57.
Coauthors: Fabrizio, M., Manduchi, C., Zannoni, G.Mengoli, G., et al., Absorption-desorption of deuterium at Pd95%-Rh5% alloy. I: Environment and temperature effects. J. Electroanal. Chem., 1995. 390: p. 135.
Coauthors: Fabrizio, M., Manduchi, C., Milli, E., Zannoni, G.Mengoli, G., et al., Absorption-desorption of deuterium at Pd95%-Rh5% alloy. II: Neutron emission. J. Electroanal. Chem., 1995. 395: p. 249.
Coauthors: Fabrizio, M., Manduchi, C., Milli, E., Zannoni, G.Mengoli, G., et al. The nickel-K2CO3, H2O system: an electrochemical and calorimetric examination. in Asti Workshop on Anomalies in Hydrogen/Deuterium Loaded Metals. 1997: Societa Italiana Di Fisica.
Coauthors: Bernardini, M., Comisso, N., Manduchi, C., Zannoni, G.Mengoli, G., et al., Anomalous heat effects correlated with electrochemical hydriding of nickel. Nuovo Cimento Soc. Ital. Fis. A, 1998. 20 D: p. 331.
Coauthors: Bernardini, M., Manduchi, C., Zannoni, G.Mengoli, G., et al., Calorimetry close to the boiling temperature of the D2O/Pd electrolytic system. J. Electroanal. Chem., 1998. 444: p. 155.
Coauthors: Bernardini, M., Manduchi, C., Zannoni, G.Menlove, H.O., et al. Measurement of Neutron Emission From Cylinders Containing Titanium With Pressurized Deuterium Gas. in Workshop on Cold Fusion Phenomena. 1989. Santa Fe, NM,.
Coauthors: Fowler, M. M., Garcia, E., Mayer, A., Miller, M. C., Ryan, R. R.Menlove, H.O. High-Sensitivity Measurements of Neutron Emission From Ti Metal in Pressurized D2 Gas. in The First Annual Conference on Cold Fusion. 1990. University of Utah Research Park, Salt Lake City, Utah: National Cold Fusion Institute.
Coauthors:Menlove, H.O., et al., Measurement of neutron emission from Ti and Pd in pressurized D2 gas and D2O electrolysis cells. J. Fusion Energy, 1990. 9(4): p. 495.
Coauthors: Fowler, M. M., Garcia, E., Miller, M. C., Paciotti, M. A., Ryan, R. R., Jones, S. E.Menlove, H.O. and M.C. Miller, Neutron-burst detectors for cold-fusion experiments. Nucl. Instrum. Methods Phys. Res. A, 1990. 299: p. 10.
Coauthors: Miller, M. C.Menlove, H.O., et al. Reproducible Neutron Emission Measurements From Ti Metal in Pressurized D2 Gas. in Anomalous Nuclear Effects in Deuterium/Solid Systems, "AIP Conference Proceedings 228". 1990. Brigham Young Univ., Provo, UT: American Institute of Physics, New York.
Coauthors: Paciotti, M. A., Claytor, T. N., Maltrud, H. R., Rivera, O. M., Tuggle, D. G., Jones, S. E.
ABSTRACT
During the past year, we have measured neutron emission from samples of titanium (Ti) metal and sponge in pressurized D2 gas. In January 1990, we improved our sample preparation procedure and our detector sensitivity level so that the neutron-emission measurements are now reproducible, but not yet predictable. We have measured excess neutron emission from the majority of our most recent samples using our high-sensitivity neutron detectors. The improved sensitivity in our new detector system was obtained by using low-radioactive-background stainless steel tubes, a small detector volume with high efficiency, and additional cosmic-ray shielding. Our most sensitive detector consists of two independent segments making up inner and outer rings of 3He tubes. The combined total efficiency is 44%. In addition to inner and outer ring segments, we have three separate detector systems operating in parallel control experiments to monitor environmental change. We have measured neutron bursts from a variety of samples containing Ti metal and D2 gas. The low-multiplicity bursts, emitting from 2 to 10 n, occur much more frequently than the higher multiplicity bursts. By measuring high-mass samples (300 g Ti) over several weeks, with many liquid nitrogen temperature cycles, we have detected neutron emission above the background from most of the samples with a significance level of 3 to 9 σ.
Menlove, H.O., et al., The measurement of neutron emission from Ti plus D2 gas. J. Fusion Energy, 1990. 9: p. 215.
Coauthors: Fowler, M. M., Garcia, E., Mayer, A., Miller, M. C., Ryan, R. R., Jones, S. E.Menlove, H.O., et al. Low-background Measurements of Neutron Emission from Ti Metal in Pressurized Deuterium Gas. in Second Annual Conference on Cold Fusion, "The Science of Cold Fusion". 1991. Como, Italy: Societa Italiana di Fisica, Bologna, Italy.
Coauthors: Paciotti, M. A., Claytor, T. N., Tuggle, D. G.
ABSTRACT
A wide variety of neutron detector systems have been used at various research facilities to search for anomalous neutron emission from deuterated metals. Some of these detector systems are summarized here together with possible sources of spurious signals from electronic noise. During the past two years, we have performed experiments to measure neutron emission from pressurized D2 gas mixed with various forms of titanium metal chips and sponge. Details concerning the neutron detectors, experimental procedures, and results have been reported previously. Our recent experiments have focused on increasing the low-level neutron emission and finding a way to trigger the emission. To improve our detection sensitivity, we have increased the shielding in our counting laboratory, changed to low-background 3He tubes, and set up additional detector systems in deep underground counting stations. This report is an update on this experimental work.
Merriman, B. and P. Burchard, An attempted replication of the CETI cold fusion experiment. 1996.
Coauthors: Burchard, P.Meulenberg, A. and K.P. Sinha. Tunneling Beneath the 4He Fragmentation Energy (PowerPoint slides). in 15th International Conference on Condensed Matter Nuclear Science. 2009. Rome, Italy: ENEA.
Coauthors: Sinha, K. P.
Abstract
At ICCF-14, we presented the means whereby the repulsive Coulomb barrier between hydrogen (deuterium) nuclei is reduced in length, perhaps by orders of magnitude. This mechanism, involving optical phonons and electric fields (internally or externally generated) in a lattice that induce the formation of H- H+ (D- D+) pairs, increases the tunneling probability by more than 100 orders of magnitude. It has additional major consequences.
The lattice constraints and collision processes force the ions into a temporary, but cyclic, 1-D configuration that greatly deepens the electron ground-state potential well. The tightly-bound and energetic electron pair (a local-charged Boson - the lochon) becomes more than strong screening, it becomes a binding force between the nuclei. Thus, the Coulomb-barrier height is reduced as well as its length. With this greatly enhanced barrier-penetration probability, the energy level of nuclei with reasonable tunneling probability drops from the multi-100 keV range down into the eV range. . . .
Meyerhof, W.E. Statistical Analysis of a Cold Fusion Experiment. in Anomalous Nuclear Effects in Deuterium/Solid Systems, "AIP Conference Proceedings 228". 1990. Brigham Young Univ., Provo, UT: American Institute of Physics, New York.
Coauthors:Meyerhof, W.E., Statistical Analysis of a 'Cold Fusion' experiment. J. Radioanal. Nucl. Chem. Lett., 1991. 153: p. 391.
Coauthors:Miao, B., Experimental exploration on possible mechanism of D-D cold fusion in titanium lattice. Xibei Shifan Daxue Xuebao, Ziran Kexueban, 1994. 30: p. 44 (in Chinese).
Coauthors:Miao, B., Experimental exploration on the possible mechanism of D-D cold fusion in titanium lattice. Xibei Shifan Xuebao. Ziran Kexueban, 1994. 30(1): p. 39 (in Chinese).
Coauthors:Michrowski, A., Advanced transmutation processes and their application for the decontamination of radioactive nuclear waste. J. New Energy, 1996. 1(3): p. 122.
Coauthors:Middleton, R., J. Klein, and D. Fink, Tritium measurements with a tandem accelerator. Nucl. Instrum. Methods Phys. Res. B, 1990. 47: p. 409.
Coauthors: Klein, J., Fink, D.Miles, M., K.H. Park, and D.E. Stilwell, Electrochemical calorimetric evidence for cold fusion in the palladium-deuterium system. J. Electroanal. Chem., 1990. 296: p. 241.
Coauthors: Park, K. H., Stilwell, D. E.Miles, M., K.H. Park, and D.E. Stilwell. Electrochemical Calorimetric Studies of the Cold Fusion Effect. in The First Annual Conference on Cold Fusion. 1990. University of Utah Research Park, Salt Lake City, Utah: National Cold Fusion Institute.
Coauthors: Park, K. H., Stilwell, D. E.Several types of calorimetric cell designs were used in attempts to measure excess enthalpy during the electrolysis of LiOD/D2O using palladium cathodes. Control experiments were run by using light water in place of D2O or by using platinum cathodes in place of palladium. Initial experiments using thin palladium cathodes of an unknown purity gave no significant differences between the Pd/D2O cells and the controls. For example, the ratio of heat out to Joule heat in was 1.00 ±0.04 for one study and 1.065 ±0.04 for another study in LiOD/D2O compared to 1.075 ±0.07 in LiOH/H2O. The use of a much thicker palladium rod (99.96%, d = 0.635 cm) from Johnson Matthey, however, resulted in calorimetric evidence for excess enthalpy in five out of six cells. The excess rate of heating averaged 0.39 W/cm3 over a 9-day period in one experiment. The total excess enthalpy observed was 110,000 J. This excess enthalpy is difficult to explain by chemical reactions. Similar experiments conducted in H2O did not produce significant amounts of excess enthalpy. Possible experimental errors in these calorimetric studies are being investigated.
Miles, M. and R.E. Miles, Theoretical neutron flux levels, dose rates, and metal foil activation in electrochemical cold fusion experiments. J. Electroanal. Chem., 1990. 295: p. 409.
Coauthors: Miles, R. E.Miles, M., et al. Heat and Helium Production in Cold Fusion Experiments. in Second Annual Conference on Cold Fusion, "The Science of Cold Fusion". 1991. Como, Italy: Societa Italiana di Fisica, Bologna, Italy.
Coauthors: Bush, B. F., Ostrom, G. S., Lagowski, J. J.Miles, M. and B.F. Bush. Calorimetric Principles and Problems in Pd-D2O Electrolysis. in Third International Conference on Cold Fusion, "Frontiers of Cold Fusion". 1992. Nagoya Japan: Universal Academy Press, Inc., Tokyo, Japan.
Coauthors: Bush, B. F.
ABSTRACT
Most of the laboratories involved with the question of excess enthalpy in Pd-D2O electrolysis experiments have employed isoperibolic calorimetric techniques. A careful re-examination of earlier results from several laboratories (California Institute of Technology, Massachusetts Institute of Technology, and Harwell Laboratory) is needed in terms of our present understanding of electrochemical calorimetry. Error sources in their experiments are discussed. There is possible evidence for excess power production in the Pd-D2O electrolysis experiments at one of these laboratories.
A significant experimental problem in many isoperibolic calorimetric studies is the fact that the decrease in the electrolyte level due to electrolysis produces a significant decrease in the calorimetric cell constant if the temperature is measured in the electrolyte of the electrochemical cell. Furthermore, heat conduction pathways out of the top of the cell can produce large errors, especially at low power levels. There is no steady state in electrochemical calorimetry, hence accurate results require the evaluation of all terms in the differential equation governing the calorimeter.
Miles, M. and C.P. Jones, Cold fusion experimenter Miles responds to critic. 21st Century Sci. & Technol., 1992. Spring: p. 75.
Coauthors: Jones, C. P.Miles, M. and B.F. Bush. Search for Anomalous Effects Involving Excess Power and Helium During D2O Electrolysis Using Palladium Cathodes. in Third International Conference on Cold Fusion, "Frontiers of Cold Fusion". 1992. Nagoya Japan: Universal Academy Press, Inc., Tokyo, Japan.
Coauthors: Bush, B. F.Miles, M., et al., Correlation of excess power and helium production during D2O and H2O electrolysis using palladium cathodes. J. Electroanal. Chem., 1993. 346: p. 99.
Coauthors: Hollins, R. A., Bush, B. F., Lagowski, J. J., Miles, R. E.
Abstract
A critical issue in determining whether or not the anomalous effects that occur during D2O electrolysis are of nuclear origin is the measurement of nuclear products in amounts sufficient to explain the rate of excess enthalpy generation. Calorimetric evidence of excess power up to 27% was measured during the electrolysis of heavy water using palladium cathodes. Maximum excess power was 0.52 W (1.5 W/cm3) at 250 mA/cm2. Eight electrolysis gas samples collected during episodes of excess power production in two identical cells and analysed by mass spectrometry showed the presence of 4He. Furthermore, the amount of helium detected correlated qualitatively with the amount of excess power and was within an order of magnitude of the theoretical estimate of helium production based upon fusion of deuterium to form 4He. Any production of 3He or neutrons in these experiments was below our detection limits. However, the exposure of dental X-ray films placed outside the cells suggests the emission of radiation. Control experiments performed in exactly the same way but using H2O + LiOH in place of D2O + LiOD gave no evidence of helium, excess power or radiation.
Miles, M. and B.F. Bush. Heat and Helium Measurements in Deuterated Palladium. in Fourth International Conference on Cold Fusion. 1993. Lahaina, Maui: Electric Power Research Institute 3412 Hillview Ave., Palo Alto, CA 94304.
Coauthors: Bush, B. F.Miles, M., Letter to Steven E. Jones. 1993.
Coauthors:Miles, M., B.F. Bush, and J.J. Lagowski, Anomalous effects involving excess power, radiation, and helium production during D2O electrolysis using palladium cathodes. Fusion Technol., 1994. 25: p. 478.
Coauthors: Bush, B. F., Lagowski, J. J.Miles, M., B.F. Bush, and D.E. Stilwell, Calorimetric principles and problems in measurements of excess power during Pd-D2O electrolysis. J. Phys. Chem., 1994. 98: p. 1948.
Coauthors: Bush, B. F., Stilwell, D. E.Miles, M. and B.F. Bush, Heat and Helium Measurements in Deuterated Palladium. Trans. Fusion Technol., 1994. 26(4T): p. 156.
Coauthors: Bush, B. F.Miles, M. The Extraction of Information From an Integrating Open Calorimeter in Fleischmann-Pons Effect Experiments. in 5th International Conference on Cold Fusion. 1995. Monte-Carlo, Monaco: IMRA Europe, Sophia Antipolis Cedex, France.
Coauthors:Miles, M. and K.B. Johnson, Anomalous Effects in Deuterated Systems, Final Report. 1996, Naval Air Warfare Center Weapons Division.
Coauthors: Johnson, K. B.
ABSTRACT
Excess power was measured in 28 out of 94 electrochemical experiments conducted using palladium or palladium‑alloy cathodes in heavy water. Reproducibility continues to be the major problem in this controversial research area. Based on our experiments, this lack of reproducibility stems from unknown variables in the palladium metal. The best reproducibility for excess power was obtained using palladium‑boron materials supplied by the Naval Research Laboratory. Our basic isoperibolic calorimeters were capable of measuring excess power with a sensitivity of "1% of the input power or "20 mW, whichever was larger. Calorimeters that are capable of detecting excess power levels of 1 watt per cubic centimeter of palladium are essential for research in this field. Results from our laboratory indicate that helium‑4 is the missing nuclear product accompanying the excess heat. Thirty out of 33 experiments showed a correlation between either excess power and helium production or no excess power and no excess helium. The collection of the electrolysis gases in both glass and metal flasks place the helium production rate at 1011 to 1012 atoms per second per watt of excess power. This is the correct magnitude for typical deuteron fusion reactions that yield helium‑4 as a product. Anomalous radiation was defected in some experiments by the use of X‑ray films, Geiger‑Mueller counters, and by the use of sodium iodide detectors. There was never any significant production of tritium in any of our experiments.
Miles, M. and K.B. Johnson, Electrochemical insertion of hydrogen into metals and alloys. Infinite Energy, 1996. 1(5 & 6): p. 68.
Coauthors: Johnson, K. B.
ABSTRACT
Hydrogen in metals has possible applications in various energy storage devices. For the palladium-deuterium system, excess power production and other anomalous effects have been reported. This study focused on hydrogen and deuterium insertion into palladium and deuterium insertion into various palladium-boron alloys. The condition of the metal surface is a major factor in the insertion of hydrogen or deuterium into palladium or palladium-boron alloys. Cracks or other surface defects prevent high loading levels of hydrogen in metals. The addition of boron to palladium does not affect the initial loading rate but slows further loading to higher levels. The presence of boron in the palladium significantly slows the rate of the deloading process.
Miles, M., K.B. Johnson, and M.A. Imam. Electrochemical loading of hydrogen and deuterium into palladium and palladium-boron alloys. in Sixth International Conference on Cold Fusion, Progress in New Hydrogen Energy. 1996. Lake Toya, Hokkaido, Japan: New Energy and Industrial Technology Development Organization, Tokyo Institute of Technology, Tokyo, Japan.
Coauthors: Johnson, K. B., Imam, M. A.
Abstract
Excess power production and other anomalous effects have been observed during the electrolysis of heavy water using palladium and palladium-boron alloys as the cathode materials. This study focused on hydrogen and deuterium loading into palladium and palladium-boron alloys. Improved calorimetry provided for the detection of the exothermic heat of absorption of deuterium into palladium and palladium-alloy cathodes. The addition of boron to palladium does not significantly affect the initial loading rate but slows further loading to higher levels. The presence of boron in the palladium significantly slows the rate of the deloading process. Cracks or other surface defects prevent high loading levels of hydrogen or deuterium into palladium or palladium-boron alloys.
Miles, M., K.B. Johnson, and M.A. Imam. Heat and Helium Measurements Using Palladium and Palladium Alloys in Heavy Water. in Sixth International Conference on Cold Fusion, Progress in New Hydrogen Energy. 1996. Lake Toya, Hokkaido, Japan: New Energy and Industrial Technology Development Organization, Tokyo Institute of Technology, Tokyo, Japan.
Coauthors: Johnson, K. B., Imam, M. A.Miles, M. and K.B. Johnson. Improved, Open Cell, Heat Conduction, Isoperibolic Calorimetry. in Sixth International Conference on Cold Fusion, Progress in New Hydrogen Energy. 1996. Lake Toya, Hokkaido, Japan: New Energy and Industrial Technology Development Organization, Tokyo Institute of Technology, Tokyo, Japan.
Coauthors: Johnson, K. B.Miles, M., Electrochemical calorimetric studies of palladium and palladium alloys in heavy water. 1998: Sapporo, Japan.
Coauthors:Miles, M. and B.F. Bush. Radiation Measurements at China Lake:Real or Artifacts? in The Seventh International Conference on Cold Fusion. 1998. Vancouver, Canada: ENECO, Inc., Salt Lake City, UT.
Coauthors: Bush, B. F.
ABSTRACT
Anomalously high radiation counts were observed using several different Geiger-Mueller (GM) detectors as well as sodium iodide (NaI) detectors during electrolysis experiments with palladium cathodes in heavy water. These high radiation counts were often observed in co-deposition experiments where palladium metal is deposited from a D2O solution onto a copper cathode in the presence of evolving deuterium gas. The anomalous radiation counts reached values as high as 73 sigma above normal background counts. The anomalous radiation would appear within a few hours in the co-deposition experiments where the palladium is loaded with deuterium as it deposits from solution. In contrast, the appearance of anomalous radiation required days of electrolysis for the palladium rods that load much slower. The real or artifact question stems mainly from the fact that two similar GM detectors often gave different results in monitoring the excess radiation. A few experiments, nevertheless, gave simultaneous anomalous effects from two different radiation detectors.
Miles, M., Reply to 'An assessment of claims of excess heat in cold fusion calorimetry'. J. Phys. Chem. B, 1998. 102: p. 3648.
Coauthors:Miles, M., Reply to 'Examination of claims of Miles et al. in Pons-Fleischmann-type cold fusion experiments'. J. Phys. Chem. B, 1998. 102: p. 3642.
Coauthors:Miles, M. Production of helium in the cold. in 18th Annual Meeting of the Society for Scientific Exploration. 1999. Albuquerque, NM.
Coauthors:Miles, M., M.A. Imam, and M. Fleischmann. "Case Studies" of Two Experiments Carried Out With the ICARUS Systems. in 8th International Conference on Cold Fusion. 2000. Lerici (La Spezia), Italy: Italian Physical Society, Bologna, Italy.
Coauthors: Imam, M. A., Fleischmann, M.Miles, M. Calorimetric Studies of Palladium Alloy Cathodes Using Fleischmann-Pons Dewar Type Cells. in 8th International Conference on Cold Fusion. 2000. Lerici (La Spezia), Italy: Italian Physical Society, Bologna, Italy.
Coauthors:New experiments in sensitive calorimeters displayed the characteristics of the excess power effect during seven different occasions. These measurements clearly show the anomalous increase in the cell temperature despite the steadily decreasing electrical input power during Pd/D2O+LiOD/Pt electrolysis. This strange behavior can be modeled by the use of an anomalous excess power term in the calorimetric equations. Two thermistors used in each calorimetric cell always show nearly identical temperature changes, thus errors due to temperature gradients within the cell are unlikely. The onset of the excess power apparently develops in a gradual manner. There were never any large, abrupt increases in the excess power. The addition of D2O with its sudden cooling of the cell generally dissipated the excess power effect. No clear triggering events for the excess power could be identified. Possible chemical explanations for the excess power are discussed. Normal behavior was always observed for a similar experiment conducted as a control.
Miles, M., Calorimetric studies of Pd/D2O+LiOD electrolysis cells. J. Electroanal. Chem., 2000. 482: p. 56.
Coauthors:My first three experiments conducted at NHE using the Fleischmann-Pons (F-P) Dewar type cells investigated the Pd-Ce-B, Pd-B, and Pd-Ce alloy cathodes. Significant excess power was produced from the cells using the Pd-B and Pd-Ce alloy cathodes. The Pd-Ce-B alloy, in contrast, showed no measureable excess power effects. Previous experiments at China Lake using similar Pd-B alloy cathodes prepared by the Naval Research Laboratory (NRL) produced excess heat in seven out of eight experiments. The same Pd-Ce cathode that was used at NHE also produced significant excess power in previous experiments at China Lake. Due to the controversy over methods of data analysis for the F-P cells (see ICCF-5 Proceedings, 1995, pp. 105-115), I developed my own methods while at NHE. As I refined my methods for evaluating the calorimetric measurements, they approached more closely the methods outlined by Fleischmann and Pons in their Icarus Systems handbooks available at NHE. The method previously developed by NHE for the analysis of the F-P cells showed no excess heat for any of these same three experiments. The major problem with the NHE method is that a single calibration was used in determining the effective radiative heat transfer coefficient for the cell. An incorrect heat transfer coefficient can readily confuse the excess heat effect with the calorimetric error for the system. Calorimetric results for the same experiment using the NHE method, my method, and the F-P method for data analysis are compared. The fact that the alternative NHE method showed no excess heat for F-P cells illustrates the problem in transferring calorimetric methods from one laboratory to another. The second laboratory often fails to follow directions and makes changes that compromise the calorimetry. Similar problems were encountered in the attempt to transfer the China Lake calorimetry to NRL, hence excess heat was not observed.
Miles, M., Report on Calorimetric Studies at the NHE Laboratory in Sapporo, Japan. Infinite Energy, 2000. 5(30): p. 22.
Coauthors:Experiments using China Lake type calorimetric cells produced excess power in three out of three experiments and no excess power in three control studies. A detailed analysis is presented for two experiments using the China Lake cells. Anomalous thermistor signals in Cell A suggest the emission of electromagnetic radiation from the active palladium cathode. Experiments in Fleischmann-Pons type calorimetric cells produced excess power in six out of eight experiments. These studies involved palladium alloy cathodes, co-deposition of palladium and deuterium from the solution, and electromigration using thin palladium wires.
Miles, M., M.A. Imam, and M. Fleischmann, Calorimetric analysis of a heavy water electrolysis experiment using a Pd-B alloy cathode. Proc. Electrochem. Soc., 2001. 2001-23: p. 194.
Coauthors: Imam, M. A., Fleischmann, M.Miles, M., M. Fleischmann, and M.A. Imam, Calorimetric Analysis of a Heavy Water Electrolysis Experiment Using a Pd-B Alloy Cathode. 2001: Washington. p. 154.
Coauthors: Fleischmann, M., Imam, M. A.Miles, M., et al. The Elevation of Boiling Points in H2O and D2O Electrolytes. in The 9th International Conference on Cold Fusion, Condensed Matter Nuclear Science. 2002. Beijing, China: Tsinghua University.: Tsinghua Univ. Press.
Coauthors: Arman, H. D., Carrick, J. D., Gren, C. K., Haggerty, K. A., Kim, H. Y., Ky, A. G., Markham, J. E., Meeks, C. F., Noga, D. E.
ABSTRACT
The excess enthalpy effect in cold fusion experiments for Pd/D2O + LiOD systems is subject to positive feedback, i.e., increasing the cell temperature increases the excess enthalpy. Therefore, the largest excess enthalpy effects are often observed near or at the boiling point corresponding to that of the electrolyte solution in the cell. The exact boiling temperatures at different electrolyte concentrations are needed for cold fusion experiments. These studies of LiOH in H2O and LiOD in D2O both show boiling point elevations at higher concentrations that are significantly lower than theoretical calculations based on ideal solutions. Activity coefficients of LiOD in D2O at the boiling point of D2O (101.42°C) are also reported. These boiling point measurements suggest a purity problem with heavy water samples that may contribute to the reproducibility problem for excess enthalpy.
Miles, M., et al. Thermal Behavior of Polarized Pd/D Electrodes Prepared by Co-deposition. in The 9th International Conference on Cold Fusion, Condensed Matter Nuclear Science. 2002. Beijing, China: Tsinghua University: Tsinghua Univ. Press.
Coauthors: Szpak, S., Mosier-Boss, P. A., Fleischmann, M.
ABSTRACT
The thermal behavior of a polarized Pd+D electrode prepared by the co-deposition technique and serving as the cathode in the Fleischmann-Pons (F/P) Dewar-type electrochemical cell/calorimeter was investigated at the NHE Laboratory in Sapporo, Japan. These measurements show that (i) excess enthalpy is generated during and after the completion of the co-deposition process, (ii) rates of excess enthalpy generation are somewhat higher than when Pd wires or other forms of Pd electrodes are used and (iii) positive feedback and heat-after-death effects were present in this system.
Miles, M. Correlation Of Excess Enthalpy And Helium-4 Production: A Review. in Tenth International Conference on Cold Fusion. 2003. Cambridge, MA: LENR-CANR.org.
Coauthors:Three different sets of experiments conducted in the Navy Laboratory (NAWCWD) at China Lake, California (1990-1994) clearly established that helium-4 is the main fusion product in the Pd/D2O+LiOD electrolysis system. A correlation between excess enthalpy and excess helium-4 was measured in 18 out of 21 experiments. The observation of no excess enthalpy was correlated with no excess helium-4 in 12 out of 12 experiments. Thus 30 out of 33 experiments agree with the hypothesis that the excess enthalpy produced in cold fusion studies is correlated with helium-4 production: D + D ® 4He + 23.8 MeV. Furthermore, the measured rate of helium-4 production was always in the appropriate range of 1010 to 1012 atoms per second per watt of excess power.
Miles, M. Fluidized Bed Experiments Using Platinum And Palladium Particles In Heavy Water. in Tenth International Conference on Cold Fusion. 2003. Cambridge, MA: LENR-CANR.org.
Coauthors:These experiments were designed to give the dynamic electrolysis conditions of fluidized beds by the use of small palladium particles. Both direct current electrolysis and pulse power electrolysis methods were used in this study. The excess power observed was 90 mW for direct current electrolysis in D2O + 0.1 M LiOD (I=0.300 to 0.400 A). For pulse electrolysis (pulse width 1.0 ms, pulse frequency 5 KHZ, peak voltage 98 V), the excess power increased to 250 mW. No excess power was observed for similar experiments using platinum particles in D2O + 0.1 M LiOD.
Miles, M., NEDO Final Report - Electrochemical Calorimetric Studies Of Palladium And Palladium Alloys In Heavy Water. 2004, University of La Verne.
Coauthors:The main feature of the FleischmannPons effect is excess heat production. My experiments designed to measure excess heat focused on the use of two types of isoperibolic calorimeters. Cells A and B transfer heat mainly by conduction while the three FleischmannPons type cells transfer heat mainly by radiation. The first set of experiments in cells A and B used palladium cathodes. Small levels of excess power were observed in Cell A but none in Cell B. This result is in agreement with previous experiments at China Lake, California using the same two palladium cathodes. There were also periods of unusual fluctuations in the temperature readings in Cell A for the thermistor closest to the cathode that persisted for several weeks. These sudden temperature increases occurred during the same time period as when the excess heat was observed. The switching of these experiments to pulse electrolysis also produced an excess heat effect in Cell A but not in Cell B.
Miles, M. Simultaneous Excess Power and Anomalous Radiation (PowerPoint slides). in American Physical Society Meeting. 2005. Los Angeles.
Coauthors:Miles, M. and M. Fleischmann. Precision and Accuracy of Cold Fusion Calorimetry (paper and PowerPoint slides). in 233rd ACS National Meeting. 2007. Chicago, IL.
Coauthors: Fleischmann, M.The cold fusion controversy centers on the precision and accuracy of the calorimetric systems used to measure excess enthalpy generation. For open, isoperibolic calorimetric systems, there is no true steady state during D2O+LiOD electrolysis. Exact calorimetric measurements, therefore, require modeling by a differential equation that accounts for all heat flow pathways into and out of the calorimetric systems. The improper use and misunderstanding of this differential equation is a major source of confusion concerning cold fusion calorimetric measurements.
Miles, M. and M. Fleischmann, Accuracy of Isoperibolic Calorimetry Used in a Cold Fusion Control Experiment, in Low-Energy Nuclear Reactions Sourcebook. 2008, American Chemical Society: Washington, DC. p. 153-171.
Coauthors: Fleischmann, M.Miles, M. and M. Fleischmann. Isoperibolic Calorimetric Measurements of the Fleischmann-Pons Effect. in ICCF-14 International Conference on Condensed Matter Nuclear Science. 2008. Washington, DC.
Coauthors: Fleischmann, M.Important advantages exist for selecting a Dewar type isoperibolic calorimeter for measurements of anomalous excess enthalpy produced by the Fleischmann-Pons Effect (FPE). These advantages include a wide dynamic range for both the cell temperature and cell input power, direct visual observations inside the cell during calorimetric experiments, relative low cost, self-purification of the system, the safety of an open system, and heat transfer mainly by electromagnetic radiation. Various generations of this calorimetry are described along with the mathematical modeling. The use of control or blank experiments, such as replacing palladium by platinum, show that anomalous excess power is measurable to within ±0.1 mW using this electrochemical calorimetry. The application of this Dewar isoperibolic calorimetry at other laboratories such as NHE (Japan), Grenoble (France) and Harwell (U.K.) is discussed. Variations of isoperibolic calorimetry used by China Lake, Caltech, and M.I.T. are also examined where the main heat transfer pathway is by conduction. An improved version of the China Lake isoperibolic calorimeter is capable of measuring the small excess power (6.5 mW) produced at the beginning of an experiment by the exothermic absorption of deuterium into palladium.
Miles, M. and M. Fleischmann. Twenty Year Review of Isoperibolic Calorimetric Measurements of the Fleischmann-Pons Effect. in ICCF-14 International Conference on Condensed Matter Nuclear Science. 2008. Washington, DC.
Coauthors: Fleischmann, M.Miles, M. and M. Fleischmann. New approaches to isoperibolic calorimetry (PowerPoint slides). in 15th International Conference on Condensed Matter Nuclear Science. 2009. Rome, Italy: ENEA.
Coauthors: Fleischmann, M.
Desired Features of Isoperibolic Calorimeters
* Simple Construction / Low Costs
* Wide Dynamic Range
- Cell Temperature (20°C --> Boiling)
- Cell Input Power (0 --> 10 Watts)
* Required kc= 0.13 W/K or kR= 0.83 x 10-9W/K^4
* Self-Purifying (H Removed Preferentially to D)
* Inherent Safety (D2, O2 Exit Cell)
* Direct Visual Observation Inside Cell (Dewar Cell)
* High Accuracy (±1 mW, ±0.1%)
* Heat Transfer Mainly By Conduction or Radiation
* Stable Cell Constants Independent of Electrolyte Level
Miley, G.H., Book Review: Cold Fusion,The Making of a Scientific Controversy by F. D. Peat. Fusion Technol., 1990. 17: p. 730.
Coauthors:Miley, G.H., O. Barnouin, and B. Temple. Detection of Reaction Products Induced in Plasma Focus Electrodes. in Anomalous Nuclear Effects in Deuterium/Solid Systems, "AIP Conference Proceedings 228". 1990. Brigham Young Univ., Provo, UT: American Institute of Physics, New York.
Coauthors: Barnouin, O., Temple, B.Miley, G.H., M. Ragheb, and H. Hora. On Aspects of Nuclear Products. in The First Annual Conference on Cold Fusion. 1990. University of Utah Research Park, Salt Lake City, Utah: National Cold Fusion Institute.
Coauthors: Ragheb, M., Hora, H.Miley, G.H., et al. Multilayer Thin Film Electrodes for Cold Fusion. in Third International Conference on Cold Fusion, "Frontiers of Cold Fusion". 1992. Nagoya Japan: Universal Academy Press, Inc., Tokyo, Japan.
Coauthors: Patel, J. U., Javedani, J., Hora, H., Kelly, J. C., Tompkins, J.Miley, G.H. Comments About Nuclear Reaction Products. in Fourth International Conference on Cold Fusion. 1993. Lahaina, Maui: Electric Power Research Institute 3412 Hillview Ave., Palo Alto, CA 94304.
Coauthors:Miley, G.H., et al., Electrolytic Cell with Multilayer Thin-Film Electrodes. Trans. Fusion Technol., 1994. 26(4T): p. 313.
Coauthors: Hora, H., Batyrbekov, E. G., Zich, R. L.Miley, G.H., et al. Energy Amplifier with Multilayer Thin Film Electrodes. in International Symposium on Cold Fusion and Advanced Energy Sources. 1994. Belarusian State University, Minsk, Belarus: Fusion Information Center, Salt Lake City.
Coauthors: Batyrbekov, E. G., Hora, H., Patel, J. U., Tompkins, J., Zich, R. K.Miley, G.H. and J.A. Patterson, Nuclear transmutations in thin-film nickel coatings undergoing electrolysis. J. New Energy, 1996. 1(3): p. 5.
Coauthors: Patterson, J. A.
ABSTRACT
Experiments using 1-mm plastic and glass microspheres coated with single and multilayers of thin films of various metals such as palladium and nickel, used in a packed-bed electrolytic cell (Patterson Power Cell configuration), have apparently produced a variety of nuclear reaction products. The analysis of a run with 650-Å film of Ni is presented here. Following a two-week electrolytic run, the Ni film was found to contain Fe, Ag, Cu, Mg, and Cr, in concentrations exceeding 2 atom % each, plus a number of additional trace elements. These elements were at the most, only present in the initial film and the electrolyte plus other accessible cell components in much smaller amounts. That fact, combined with other data, such as deviations from natural isotope abundances, seemingly eliminates the alternate explanation of impurities concentrating in the film.
Miley, G.H., et al. Quantitative observations of transmutation products occuring in thin-film coated microspheres during electrolysis. in Sixth International Conference on Cold Fusion, Progress in New Hydrogen Energy. 1996. Lake Toya, Hokkaido, Japan: New Energy and Industrial Technology Development Organization, Tokyo Institute of Technology, Tokyo, Japan.
Coauthors: Narne, G., Williams, M. J., Patterson, J. A., Nix, J., Cravens, D., Hora, H.Miley, G.H., Possible Evidence of Anomalous Energy Effects in H/D-Loaded Solids-Low Energy Nuclear Reactions (LENRS). J. New Energy, 1997. 2(3/4): p. 6.
Coauthors:Miley, G.H. Product Characteristics and Energetics in Thin-Film Electrolysis Experiments. in The Seventh International Conference on Cold Fusion. 1998. Vancouver, Canada: ENECO, Inc., Salt Lake City, UT.
Coauthors:Miley, G.H. Emerging physics for a breakthrough thin-film electrolytic power unit. in Space Technol. Applic. Int. Forum. 1999.
Coauthors:Miley, G.H., et al. Advances in Thin-Film Electrode Experiments. in 8th International Conference on Cold Fusion. 2000. Lerici (La Spezia), Italy: Italian Physical Society, Bologna, Italy.
Coauthors: Selvaggi, G., Tate, A., Okuniewski, M., Williams, M. J., Chicea, D., Horn, H., Kelly, J.Miley, G.H. On the Reaction Product and Heat Correlation for LENRs. in 8th International Conference on Cold Fusion. 2000. Lerici (La Spezia), Italy: Italian Physical Society, Bologna, Italy.
Coauthors:
Abstract
Low Energy Nuclear Reactions, or LENRs, typically involve electrolytes containing light water along with electrodes made of metals such as Ni, Ti and Pd. In these experiments a variety of reaction products (isotopes), with masses both higher and lower than that of the host electrode material, have been observed at the University of Illinois (U of IL). Related results, often termed transmutation studies, have been reported by other researchers. These observations suggest that proton-metal initiated reactions occur in such LENR cells. This paper discusses evidence that the production of these reaction products is correlated with the excess heat also frequently observed in LENR cells. Such a correlation for LENR reactions would be equivalent, in principle, to the correlation of He-4 with excess heat that is reported for heavy water-Pd experiments where a D-D reaction is postulated.
Miley, G.H., Some personal reflections on scientific ethics and the cold fusion 'episode'. Accountability Res., 2000. 8: p. 121.
Coauthors:This note was prepared in response to Dr. Scott Chubbs invitation to discuss issues concerning ethics in scientific research that I may have observed during the hectic period following the public announcement of Cold Fusion (CF) by Drs. Pons and Fleischmann in 1989. I would like to preface this note with some reflections on select events I was personally involved in as editor of Fusion Technology (FT) and as one of the early researchers in CF (who has persistently kept going!). Then I will discuss several ethical issues relating to scientific conduct from my viewpoint as an editor and researcher in the field.
Miley, G.H., et al. Progress in Development of a Low Energy Reaction Cell for Distributed Power Applications. in 10th International Conference on Nuclear Engineering. 2002. Arlington, Virginia, USA: ASME.
Coauthors: Castano, C. H., Lipson, A. G., Kim, S-O., Luo, N.Miley, G.H., et al. Progress in thin-film LENR research at the University of Illinois. in The 9th International Conference on Cold Fusion, Condensed Matter Nuclear Science. 2002. Tsinghua Univ., Beijing, China: Tsinghua Univ. Press.
Coauthors: Hora, H., Lipson, A. G., Kim, S-O., Luo, N., Castano, C. H., Woo, T.
ABSTRACT
The research described here includes work on fabrication techniques for reproducible thin-film electrodes. Runs with these electrodes in a newly fabricated high sensitivity calorimetry bank is shown to provide added support for earlier excess heat production observed with ultra-high proton loadings in thin film electrodes. In addition, new in-situ radiation emission studies have discovered MeV alpha-proton emission, supporting earlier reaction product evidence of the nuclear origin of the excess heat. Recent experiments and lattice simulation studies have provided added insight into highly loaded thin film phenomena, including possible H- effects associated with anomalous resistivity effects at ultra-high loadings. . . .
Miley, G.H. and P. Shrestha. Review Of Transmutation Reactions In Solids. in Tenth International Conference on Cold Fusion. 2003. Cambridge, MA: LENR-CANR.org.
Coauthors: Shrestha, P.Transmutation reactions in highly loaded hydrides have been reported by a number of research groups. These studies are briefly summarized with emphasis on common systematics and key signatures. Transmutations divide into two types: heavy intermediate compound nucleus reactions yielding an array of products with a large spectrum of masses; direct reactions between H/D and the electrode metal or impurity atoms yielding isolated single products. Various mechanisms have been proposed to explain the products and the ability to overcome the extremely large Columbic repulsion of the high-Z elements involved. Here we briefly consider a model involving orbital mixing and virtual neutron formation associated with charge accumulation and hydrogen/deuteron flow at highly loaded interfaces.
Miley, G.H., et al. Intense non-linear soft x-ray emission from a hydride target during pulsed D bombardment (PowerPoint slides). in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Lipson, A. G., Helgeston, W., Hora, H., Luo, N., Yang, Y., Romer, M., Smith, R.PowerPoint slides for the paper of the same title.
Miley, G.H., et al. Intense non-linear soft x-ray emission from a hydride target during pulsed D bombardment. in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Lipson, A. G., Helgeston, W., Hora, H., Luo, N., Yang, Y., Romer, M., Smith, R.Radiation emission from Low Energy Nuclear Radiation (LENR) electrodes (both charged-particle and x-rays) represents an important feature of LENR in general. Here, calibration, measurement techniques, and soft x-ray emission results from deuterium bombardment of a Pd target (cathode) placed in a pulsed deuterium glow discharge (PGD) are described. An x-ray intensity of 13.4 mW/cm2 and a dose of 3.3 μJ/cm2 were calculated over a 0.5 ms pulse time from AXUV photodiode radiation detector measurements. A most striking feature is that x-ray energies > 600 V are observed with a discharge voltage only about half of that value. To further investigate this phenomenon, emission during room temperature D-desorption from electrolytically loaded Pd:Dx cathodes was also studied. The x-ray emission energy observed was quite similar to the PGD case. However, the intensity in this case was almost 13 orders of magnitude lower due to the much lower deuterium fluxes involved.
Miley, G.H., et al. On Aspects of Complex Nuclei in LENR Relative to Transmutation Reactions and X-ray Emission from Localized Clusters. in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Lipson, A. G., Yang, Y., Romer, M., Hora, H.Miley, G.H. and P. Shrestha. Overview of Light Water/Hydrogen-based Low Energy Nuclear Reaction (PowerPoint slides). in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Shrestha, P.This paper reviews light water and hydrogen-based Low Energy Nuclear Reactions (LENRs) including the different methodologies used to study these reactions and the results obtained. Reports of excess heat production, transmutation reactions and nuclear radiation emission are cited. An aim of this review is to present a summary of the present status of light water LENR research and provide some insight into where this research is heading.
Miley, G.H. and P. Shrestha. Overview of Light Water/Hydrogen-based Low Energy Nuclear Reactions. in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Shrestha, P.PowerPoint slides for the paper of the same name.
Miley, G.H., G. Narne, and T. Woo, Use of combined NAA and SIMS analyses for impurity level isotope detection. J. Radioanal. Nucl. Chem., 2005. 263(3): p. 691-696.
Coauthors: Narne, G., Woo, T.Miley, G.H., et al. Cluster Reactions in Low Energy Nuclear Reactions (LENRs). in 8th International Workshop on Anomalies in Hydrogen / Deuterium Loaded Metals. 2007. Sicily, Italy.
Coauthors: Hora, H., Lipson, A. G., Leon, H., Shrestha, J.Miley, G.H., et al. Future Power Generation by LENR with Thin-Film Electrodes (PowerPoint slides). in 233rd ACS National Meeting. 2007. Chicago, IL.
Coauthors: Hora, H., Lipson, A. G., Luo, N., Shrestha, J.PowerPoint slides from the ACS 233rd Annual Meeting, Chicago, Il March 29, 2007
Miley, G.H. Preparata Medal Lecture - A Tribute to Giuliano Preparata, a TRUE Pioneer in Cold Fusion Theory. in 8th International Workshop on Anomalies in Hydrogen / Deuterium Loaded Metals. 2007. Sicily, Italy.
Coauthors:Miley, G.H., A Fascinating Review of the Emerging Science of LENRs. 21st Century Sci. & Technol., 2008. 61.
Coauthors:World Scientifics advertisement for this book explains that, One of the most important discoveries of this century -- cold fusion -- was summarily rejected by science and the media before sufficient evidence had been accumulated to make a rational judgment possible. Enough evidence is now available to show that this rejection was wrong and that the discovery of a new source of clean energy may help solve some serious problems currently facing mankind. The book catalogues and evaluates this evidence and shows why the initial reaction was driven more by self-interest than fact.
Miley, G.H., H. Hora, and X. Yang. Condensed Matter "Cluster" Reactions in LENRs. in ICCF-14 International Conference on Condensed Matter Nuclear Science. 2008. Washington, DC.
Coauthors: Hora, H., Yang, X.In this paper we first point out evidence for condensed matter cluster formation based on thin-film electrolysis. Next, measurements of superconductivity in condensed matter deuterium clusters in dislocation sites loaded-deloaded palladium thin films are briefly reviewed, followed by a discussion of techniques under study to increase the number of such sites per unit volume of the electrodes. Estimates for resulting cluster reaction rates -- flow enhanced Pycnonuclear fusion are given. If successful, this approach offers a Roadmap for future power unit based on thin films and clusters.
Miley, G.H. Summary of the Transmutation Workshop held in association with ICCF-14. in ICCF-14 International Conference on Condensed Matter Nuclear Science. 2008. Washington, DC.
Coauthors:Miley, G.H. and J. Shrestha, Transmutation Reactions and Associated Low-Energy Nuclear Reactions Effects in Solids, in Low-Energy Nuclear Reactions Sourcebook. 2008, American Chemical Society: Washington, DC. p. 173-218.
Coauthors: Shrestha, J.Miley, G.H., et al. Clusters with Picometer Distance of Deuterons and LENR (PowerPoint slides). in 15th International Conference on Condensed Matter Nuclear Science. 2009. Rome, Italy: ENEA.
Coauthors: Yang, X., Hora, H., Andersson, L., Holmlid, L., Lipson, A.The probability of pm-Ms reactions for low energy nuclear reactions LENR and the semiempirical derivation of 2 pm deuteron screening on palladium with a reduction factor 14 in Coulomb repulsion compared with a usual plasma factor 5 was confirmed later by direct experiments. Generation of 2pm distance clusters of about 150 deuterons based on this screening and possibly by a Casimir force permitted understanding of compound reactions as measured with the 155 nucleon minimum measured at LENR. These kinds of deuteron clusters were directly measured by SQUID. Based on screening and comparable values of a Wigner-Seitz radius for very dense deuteron clusters of stable Rydberg matter in defects of iron oxide with measured 2.3 pm nuclear distance is another access which may lead to an understanding of the LENR processes.
Miley, G.H., et al., Radiochemical Comparisons on Low Energy Nuclear Reactions and Uranium, in Low-Energy Nuclear Reactions and New Energy Technologies Sourcebook Volume 2. 2009, American Chemical Society: Washington DC. p. 235-252.
Coauthors: Hora, H., Philberth, K., Lipson, A., Shrestha, P. J.Miljanic, S., et al., An attempt to replicate cold fusion claims. Fusion Technol., 1990. 18: p. 340.
Coauthors: Jevtic, N., Pesic, S., Ninkovic, M., Nikolic, D., Josipovic, M., Petkovska, L. J., Bacic, S.Miller, R.J., T.O. Brun, and C.B. Satterthwaite, Magnetic Susceptibility of Pd-H and Pd-D at Temperatures Between 6 and 150 K. Phys. Rev. B: Mater. Phys., 1978. 18: p. 5054.
Coauthors: Brun, T. O., Satterthwaite, C .B.Mills, R.L. and J.J. Farrell, A New Atomic Theory. 1990.
Coauthors: Farrell, J. J.Mills, R.L. and P. Kneizys, Excess heat production by the electrolysis of an aqueous potassium carbonate electrolyte and the implications for cold fusion. Fusion Technol., 1991. 20: p. 65.
Coauthors: Kneizys, P.Mills, R.L., Reply to 'Comments on "Excess heat production by the electrolysis of an aqueous potassium carbonate electrolyte and the implications for cold fusion"'. Fusion Technol., 1992. 21: p. 96.
Coauthors:Mills, R.L., W.R. Good, and R.M. Shaubach, Dihydrino molecule identification. Fusion Technol., 1994. 25: p. 103.
Coauthors: Good, W. R., Shaubach, R. M.Mills, R.L. and W.R. Good, Fractional quantum energy levels of hydrogen. Fusion Technol., 1995. 28: p. 1697.
Coauthors: Good, W. R.Mills, R.L., Comments on 'Interaction of palladium/hydrogen and palladium/deuterium to measure the excess energy per atom for each isotope'. Fusion Technol., 1998. 33: p. 384.
Coauthors:Mills, R.L. and W.R. Good, various papers. 1999: Blacklight Power.
Coauthors: Good, W. R.Mills, R.L., Lower-energy hydrogen methods and structures. 2000: US 6,024,935.
Coauthors:Mills, R.L., Novel Hydrogen Compounds from a Potassium Carbonate Electrolytic Cell. Fusion Technol., 2000. 37: p. 157.
Coauthors:Mills, R.L., et al., Identification of compounds containing novel hydride ions by nuclear magnetic resonance spectroscopy. J. Hydrogen Energy, 2001. 26: p. 965.
Coauthors: Dhandapani, B., Nansteel, M., He, J., Voigt, A.Mills, R.L., et al., Comparison of excessive Balmer alpha line broadening of glow discharge and microwave hydrogen plasmas with certain catalysts. J. Appl.Phys., 2002. 92: p. 7008.
Coauthors: Ray, P. C., Dhandapani, B., Mayo, R. M., He, J.Mills, R.L. and P. Ray, Spectral Emission of Fractional Quantum Energy Levels of Atomic Hydrogen from a Helium-Hydrogen Plasma and the Implications for Dark Matter. J. Hydrogen Eng., 2002. 27: p. 301.
Coauthors: Ray, P.Mills, R.L. and P. Ray, The Grand Unified Theory of Classical Quantum Mechanics. J. Hydrogen Eng., 2002. 27: p. 565.
Coauthors: Ray, P.Mills, R.L. and P. Ray, Vibrational Spectral Emission of Fractional-Principal-Quantum-Energy-Level Hydrogen Molecule Ion. J. Hydrogen Eng., 2002. 27: p. 533.
Coauthors: Ray, P.Mills, R.L., Author's Response to a Letter to the Editor. Int. J. Hydrogen Energy, 2003. 28: p. 359.
Coauthors:Milton, R., Forbidden science. Suppressed research that could change our lives. 1994, London: Fourth Estate.
Coauthors:Minari, T., et al. Experiments on Condensed Matter Nuclear Events in Kobe University. in Eleventh International Conference on Condensed Matter Nuclear Science. 2004. Marseille, France.
Coauthors: Nishio, R., Taniike, A., Furuyama, Y., Kitamura, A.We review three kinds of experimental work underway in our laboratory to investigate nuclear events in solid or liquid materials. The largest effort has been given to experiments to confirm the 7Li(d,n2a) reaction rate enhancement reaching 1015 in liquid lithium which was reported by H. Ikegami et al. [4] Li liquid droplets are formed as targets, and to keep them as pure as possible, we built a liquid Li loop. Thus far, in all cases of irradiation at the temperature from 520 to 570 K with 10 - 24 keV deuterons, we have not been able to reproduce the Ikegami enhancement for the 7Li(d,n2a) reaction.
Minato, J., et al. Materials/Surface Aspects of Hydrogen/Deuterium Loading into Pd Cathode. in 5th International Conference on Cold Fusion. 1995. Monte-Carlo, Monac: IMRA Europe, Sophia Antipolis Cedex, France.
Coauthors: Nakata, T., Denzumi, S., Yamamoto, Y., Takahashi, A., Aida, H., Tsuchida, Y., Akita, H., Kunimatsu, K.Mintmire, J.W., et al., Chemical forces associated with deuterium confinement in palladium. Phys. Lett. A, 1989. 138(1,2): p. 51.
Coauthors: Dunlap, B. I., Brenner, D. W., Mowrey, R. C., Ladouceur, H. D., Schmidt, P. P., White, C. T., O'Grady, W. E.Miskelly, G.M., et al., Analysis of the published calorimetric evidence for electrochemical fusion of deuterium in palladium. Science, 1989. 246: p. 793.
Coauthors: Heben, M. J., Kumar, A., Penner, R. M., Sailor, M. J., Lewis, N. S.Mitsuishi, N., T. Yuki, and I. Ichihara, Characteristics of the Permeation of Hydrogen-Inlet Gas Mixtures Through a Palladium Alloy Tube Wall. J. Less-Common Met., 1983. 89: p. 415.
Coauthors: Yuki, T., Ichihara, I.Miura, H. Study On Formation Of Tetrahedral Or Octahedral Symmetric Condensation By Hopping Of Alkali Or Alkaline-Earth Metal (PowerPoint slides). in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors:Miura, H. Study On Formation Of Tetrahedral Or Octahedral Symmetric Condensation By Hopping Of Alkali Or Alkaline-Earth Metal. in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors:Formation of tetrahedral or octahedral condensation related to the experiments on electrolysis or deuterium permeation was studied. We obtained the scenario about the formation that alkali or alkaline-earth metal ions infiltrating into the host metal made cavities there when they hopped onto the other sites of the crystal lattice of it, then through squeezing of H+/D+ ions in the cavity tetrahedral or octahedral condensation of protons/deuterons is caused.
Miyake, M., et al. Absorption and Desorption Behavior of Hydrogen by Neutron Irradiated Titanium. in 2nd Topical Meeting on Fusion Reactor Materials. 1981. Seattle.
Coauthors: Hirooka, Y., Shinmura, H., Yamanaka, S., Sano, T., Higashiguchi, Y.Miyamaru, H. and A. Takahashi. Periodically Current-Controlled Electrolysis of D2O/Pd System for Excess Heat Production. in Third International Conference on Cold Fusion, "Frontiers of Cold Fusion". 1992. Nagoya Japan: Universal Academy Press, Inc., Tokyo, Japan.
Coauthors: Takahashi, A.Miyamaru, H., et al. Search for Nuclear Products of Cold Fusion. in Fourth International Conference on Cold Fusion. 1993. Lahaina, Maui: Electric Power Research Institute 3412 Hillview Ave., Palo Alto, CA 94304.
Coauthors: Chimi, Y., Inokuchi, T., Takahashi, A.Miyamoto, M., et al. Deuterium ion beam irradiation of palladium under in situ control of deuterium density. in The 9th International Conference on Cold Fusion, Condensed Matter Nuclear Science. 2002. Tsinghua Univ., Beijing, China: Tsinghua Univ. Press.
Coauthors: Awa, Y., Kubota, N., Tamiike, A., Furuyama, Y., Kitamura, A.Miyamoto, S., et al. Measurement of Protons and Observation of the Change of Electrolysis Parameters in the Galvanostatic Electrolysis of the 0.1M-LiOD/D2O Solution. in Second Annual Conference on Cold Fusion, "The Science of Cold Fusion". 1991. Como, Italy: Societa Italiana di Fisica, Bologna, Italy.
Coauthors: Sueki, K., Iwai, H., Fujii, M., Shirakawa, T., Miura, H., Watanabe, T., Toriumi, H., Uehara, T., Nakamitsu, Y., Chiba, M., Hirose, T., Nakahara, H.Miyamoto, S., et al. Movement of Li During Electrolysis of 0.1M-LiOD/D2O Solution. in Fourth International Conference on Cold Fusion. 1993. Lahaina, Maui: Electric Power Research Institute 3412 Hillview Ave., Palo Alto, CA 94304.
Coauthors: Sueki, K., Kobayashi, K., Fujii, M., Chiba, M., Nakahara, H., Shirakawa, T., Kobayashi, T., Yanokura, M., Aratani, M.Mizuno, T., T. Akimoto, and N. Sato, Neutron evolution from annealed palladium cathode in LiOD-D2O solution. Denki Kagaku, 1989. 57: p. 742.
Coauthors: Akimoto, T., Sato, N.Mizuno, T., et al., Tritium evolution during cathode polarization of palladium electrode in D2O solution. Denki Kagaku, 1991. 59: p. 798 (in Japanese).
Coauthors: Akimoto, T., Azumi, K., Sato, N.Mizuno, T., et al. Cold Fusion Reaction Products and Behavior of Deuterium Absorption in Pd Electrode. in Third International Conference on Cold Fusion, "Frontiers of Cold Fusion". 1992. Nagoya Japan: Universal Academy Press, Inc., Tokyo, Japan.
Coauthors: Akimoto, T., Azumi, K., Enyo, M.Mizuno, T., et al., Diffusion rate of deuterium in Pd during cathodic charging. Denki Kagaku oyobi Kogyo Butsuri Kagaku, 1992. 60: p. 405 (Japanese, with English abstract).
Coauthors: Akimoto, T., Azumi, K., Enyo, M.Mizuno, T., et al. Anomalous Heat Evolution from SrCeO3-Type Proton Conductors during Absorption/Desorption in Alternate Electric Field. in Fourth International Conference on Cold Fusion. 1993. Lahaina, Maui: Electric Power Research Institute 3412 Hillview Ave., Palo Alto, CA 94304.
Coauthors: Enyo, M., Akimoto, T., Azumi, K.Mizuno, T., et al., Formation of 197Pt radioisotopes in solid state electrolyte treated by high temperature electrolysis in D2 gas. Infinite Energy, 1995. 1(4): p. 9.
Coauthors: Inoda, K., Akimoto, T., Azumi, K., Kitaichi, M., Kurokawa, K., Ohmori, T., Enyo, M.Mizuno, T., Analysis of Elements for Solid State Electrolyte in Deuterium Atmosphere during Applied Field. J. New Energy, 1996. 1(1): p. 79.
Coauthors:
ABSTRACT
A proton conductor, the solid state electrolyte, made from oxide of strontium, cerium, niobium and yttrium can be charged in a hot D2 gas atmosphere to produce excess heat. Anomalous heat evolution was observed for 12 in 80 cases of the samples charged by alternating current for 5 to 45 Volts at temperatures ranging from 400 to 700(C. Several kinds of alkali metals, Ca, Mg, Bismuth, Lantanides and Aluminum were locally segregated and distributed around the melted and swelled parts of the samples that generated an excess heat.
Mizuno, T., et al., Anomalous heat evolution from a solid-state electrolyte under alternating current in high-temperature D2 gas. Fusion Technol., 1996. 29: p. 385.
Coauthors: Akimoto, T., Azumi, K., Kitaichi, M., Kurokawa, K.Mizuno, T., T. Ohmori, and M. Enyo, Anomalous Isotopic Distribution in Palladium Cathode After Electrolysis. J. New Energy, 1996. 1(2): p. 37.
Coauthors: Ohmori, T., Enyo, M.Mizuno, T., et al., Anomalous isotopic distribution of elements deposited on palladium induced by cathodic electrolysis. Denki Kagaku oyobi Kogyo Butsuri Kagaku, 1996. 64: p. 1160 (in Japanese).
Coauthors: Ohmori, T., Kurokawa, K., Akimoto, T., Kitaichi, M., Inoda, K., Azumi, K., Shimokawa, S., Enyo, M.
ABSTRACT
It was confirmed by several analytic methods that reaction products with mass number ranging from 20 to 28, 46 to 54, and 72 to 82 are produced in palladium cathodes subjected to electrolysis in a heavy water solution at high pressure, high temperature, and high current density for one month. Isotopic distributions were radically different from the natural ones.
Mizuno, T., T. Ohmori, and M. Enyo, Isotopic changes of the reaction products induced by cathodic electrolysis in Pd. J. New Energy, 1996. 1(3): p. 31.
Coauthors: Ohmori, T., Enyo, M.
ABSTRACT
It was confirmed by several analytic methods that reaction products with mass numbers ranging from 6 to 220 are deposited on palladium cathodes subjected to electrolysis in a heavy water solution at high pressure, high temperature, and high current density for one month. These masses were composed of many elements ranging from hydrogen to lead. Isotopic distributions for the produced elements were radically different from the natural ones.
Mizuno, T., et al., Anomalous gamma peak evolution from SrCe solid state electrolyte charged in D2 gas. Int. J. Hydrogen Energy, 1997. 22: p. 23.
Coauthors: Inoda, K., Akimoto, T., Azumi, K., Kitaichi, M., Kurokawa, K., Ohmori, T., Enyo, M.Mizuno, T., et al., Confirmation of the changes of isotopic distribution for the elements on palladium cathode after strong electrolysis in D2O solutions. Int. J. Soc. Mat. Eng. Resources, 1998. 6(1): p. 45.
Coauthors: Akimoto, T., Ohmori, T., Enyo, M.Mizuno, T. and T. Ohmori, Neutron and Heat Generation Induced by Electric Discharge. J. New Energy, 1998. 3(1): p. 33.
Coauthors: Ohmori, T.Mizuno, T., Nuclear Transmutation: The Reality of Cold Fusion. 1998, Concord, NH: Infinite Energy Press.
Coauthors:The announcement of cold fusion in March 1989 at the University of Utah was greeted with worldwide hysteria. Drs. Martin Fleischmann and Stanley Pons had claimed that an electrochemical cell with heavy water electrolyte and a palladium cathode put out so much excess energy that the mysterious phenomenon had to be nuclear, and was probably a process related to nuclear fusion. Newspapers and magazines said it might be a major scientific discovery with the potential to end the energy crisis and revolutionize society. For a few heady weeks the public took it seriously and waited anxiously for laboratories to replicate the results. Many scientists quickly took sides for or against cold fusion mostly against. Then, by the end of the summer of 1989 the official word came, in an authoritative report written by a select panel of experts under the auspices of the Department of Energy: cold fusion was a bust. It did not exist. It was an experimental error. It could not be reproduced. Nearly every scientific journal, magazine and newspaper on earth reported this, and cold fusion abruptly dropped out of the headlines. The story, it seemed, was over. Actually, it had barely begun. Only a few thousand electrochemists in the world were qualified to do the experiments, and most of them were too busy or not interested in trying. In that autumn as public interest faded and the U.S. Department of Energy pronounced a death sentence, a small number of experienced scientists prepared serious, full-scale experiments. One of them was Tadahiko Mizuno, an assistant professor who had been doing similar electrochemical experiments for more than twenty years.
Mizuno, T., T. Ohmori, and T. Akimoto. Probability of Neutron and Heat Emission from Pt Electrode Induced by Discharge in Alkaline Solution. in The Seventh International Conference on Cold Fusion. 1998. Vancouver, Canada: ENECO, Inc., Salt Lake City, UT.
Coauthors: Ohmori, T., Akimoto, T.Mizuno, T., et al. Confirmation of Heat Generation and Anomalous Element Caused by Plasma Electrolysis in the Liquid. in 8th International Conference on Cold Fusion. 2000. Lerici (La Spezia), Italy: Italian Physical Society, Bologna, Italy.
Coauthors: Ohmori, T., Azumi, K., Akimoto, T., Takahashi, A.
Abstract
Plasma was formed on the electrode surface in a liquid electrolyte when a metal cathode was polarized in high voltage electrolysis in the solution. During the plasma electrolysis large amounts of heat are sometimes generated. The heat can exceed input substantially, in some cases by up to 200 percent of input power. At the same time, anomalous elements are detected in the electrolyte and on the electrode surface. Based on the heat and the product, we hypothesize a nuclear reaction can be induced by photon activation on the cathode element.
Mizuno, T. Experimental Confirmation of the Nuclear Reaction at Low Energy Caused by Electrolysis in the Electrolyte. in Proceedings for the Symposium on Advanced Research in Energy Technology 2000. 2000. Hokkaido University.
Coauthors:
Section 1. Confirmation with a palladium electrode in the heavy water electrolyte.
1.1 Summary
Many elements on Pd electrodes were confirmed by several analytic methods; reaction products with the mass number up to 208 are deposited on palladium cathodes, which were subjected to electrolysis in a heavy water solution at high pressure, temperature, and current density for prolonged time. These masses were composed of many elements ranging from hydrogen to lead. Extraordinary changes of their isotopic distributions in the produced elements were observed; these were radically different from the ones found in nature. Essentially the same phenomenon was confirmed eight times with high reproducibility at high cathodic current density, above 0.2 A/cm2. All the possibilities of contamination had been carefully eliminated by several pretreatments for the sample and electrolysis system. It means that a nuclear reaction had taken place during the electrochemical treatment. To explain the production of radiation-less fission-like foreign elements claimed by several electrolysis experiments with Pd cathodes, a selective channel fission model by low-energy multi-photon excitation and collective deformation is proposed. Channel-dependent fission barriers are calculated based on liquid drop model potentials for about 530 scission channels of 6 Pd isotopes with positive Q-values. Mass-distribution, Z-distribution and unnatural isotopic ratios of fission fragments as stable isotopes by the present theory have shown qualitative agreements with the experiments.
Mizuno, T., et al., Production of Heat During Plasma Electrolysis. Jpn. J. Appl. Phys. A, 2000. 39: p. 6055.
Coauthors: Ohmori, T., Akimoto, T., Takahashi, A.Plasma was formed on the surface of an electrode in a liquid solution when metal cathodes underwent high-voltage electrolysis. A real-time heat calibration system was designed for detecting the amount of heat generated during plasma electrolysis. The measured heat exceeded the input power substantially, and in some cases 200% of the input power. The heat generation process depended on the conditions for electrolysis. There was no excess heat at the beginning of plasma electrolysis. However, after plasma electrolysis for a long time, a large amount of heat was generated. The reproducibility would be 100% if all factors such as temperature, voltage and duration were optimized. Based on the heat and the products, we hypothesize that some unique reaction occurs on the cathode surface. This reaction may not occur at energy levels available during electrochemical electrolysis.
Mizuno, T., et al., Neutron Evolution from a Palladium Electrode by Alternate Absorption Treatment of Deuterium and Hydrogen. Jpn. J. Appl. Phys. A, 2001. 40(9A/B): p. L989-L991.
Coauthors: Akimoto, T., Ohmori, T., Takahashi, A., Yamada, H., Numata, H.We observed neutron emissions from palladium after it absorbed deuterium from heavy water followed by hydrogen from light water. The neutron count, the duration of the release and the time of the release after electrolysis was initiated all fluctuated considerably. Neutron emissions were observed in five out of ten test cases. In all previous experiments reported, only heavy water was used, and light water was absorbed only in accidental contamination. Compared to these deuterium results, the neutron count is orders of magnitude higher, and reproducibility is much improved.
Mizuno, T., et al. Relation Between Neutron Evolution and Deuterium Permeation With a Palladium Electrode. in The 9th International Conference on Cold Fusion, Condensed Matter Nuclear Science. 2002. Beijing, China: Tsinghua University: Tsinghua Univ. Press.
Coauthors: Akimoto, T., Ohmori, T., Takahashi, A.
Abstract
We observed neutron emissions from palladium after it absorbed deuterium from heavy water followed by hydrogen from light water. The neutron count, the duration of the release and the time of the release after electrolysis was initiated all fluctuated considerably. Neutron emissions were observed in five out of ten test cases. In all previous experiments reported, only heavy water was used, and light water was absorbed only in accidental contamination. Compared to these deuterium results, the neutron count is orders of magnitude higher, and reproducibility is much improved.
Mizuno, T., T. Akimoto, and T. Ohmori. Confirmation of anomalous hydrogen generation by plasma electrolysis. in 4th Meeting of Japan CF Research Society. 2003. Iwate, Japan: Iwate University.
Coauthors: Akimoto, T., Ohmori, T.Abstract: Direct decomposition of water is very difficult in normal conditions. Hydrogen gas is usually obtained by the electrolysis. Pyrolysis decomposition of water occurs at high temperatures, starting at ~3000ºC. As we have already reported, anomalous hydrogen is sometimes generated during plasma electrolysis. Excess hydrogen usually appears once certain difficult conditions during high temperature glow discharge electrolysis are met. Here, we show that anomalous amounts of hydrogen and oxygen gas are generated during plasma electrolysis excess gas generation, presumably from pyrolysis. This is indirect proof that exceptionally high temperatures have been achieved. (Direct measurement of the reaction temperature has proved difficult.) Continuous generation of hydrogen above levels predicted by Faradays law is observed when temperature, current density, input voltage and electrode surface meet certain conditions. Although only a few observations of excess hydrogen gas production have been made, production is sometimes 80 times higher than normal Faradic electrolysis gas production.
Mizuno, T., T. Ohmori, and T. Akimoto. Generation of Heat and Products During Plasma Electrolysis. in Tenth International Conference on Cold Fusion. 2003. Cambridge, MA: LENR-CANR.org.
Coauthors: Ohmori, T., Akimoto, T.Abstract: Direct decomposition of water is very difficult to achieve in normal conditions. Hydrogen gas can be usually obtained by electrolysis and a pyrolysis reaction at high temperatures above 3700 degrees Celsius. However, as we have already reported, anomalous heat generation during plasma electrolysis is relatively easy to obtain under the right simultaneous conditions of high temperature and electrolysis. In this paper we discuss the anomalous amount of hydrogen and oxygen gas generated during plasma electrolysis. The generation of hydrogen in amounts exceeding Faradays law is continuously observed when the conditions such as temperature, current density, input voltage and electrode surface are suitable. Non-Faradic generation of hydrogen gas is sometimes 80 times higher than the gas from normal electrolysis. Excess hydrogen has proved difficult to replicate by other laboratories, although we are able to reproduce it regularly.
Mizuno, T., et al. Generation of Heat and Products During Plasma Electrolysis. in Eleventh International Conference on Condensed Matter Nuclear Science. 2004. Marseille, France.
Coauthors: Chung, D., Sesftel, F., Aoki, Y.Abstract: Direct decomposition of water is very difficult in normal conditions. Hydrogen gas can be usually obtained by electrolysis or by a pyrolysis reaction at high temperatures, starting at approximately 3700ºC. However, as we have already reported, anomalous heat generation can occur during plasma electrolysis, and this process makes it rather easy to achieve both electrolysis and pyrolysis simultaneously. In this paper we describe anomalous amounts of hydrogen and oxygen gas generated during plasma electrolysis. The generation of hydrogen far in excess of amounts predicted by Faradays law is continuously observed when conditions such as temperature, current density, input voltage and electrode surface are suitable. Non-Faraday generation of hydrogen gas sometimes produces more than 80 times as much hydrogen as normal electrolysis does. Unfortunately there have been few claimed replications of excess hydrogen, even in rare cases in which excess heat is claimed. In most cases, no excess heat or hydrogen is observed. The reaction products found after electrolysis were different after excess heat generation.
Mizuno, T., et al. Neutron emission from D2 gas in magnetic fields under low temperature. in Eleventh International Conference on Condensed Matter Nuclear Science. 2004. Marseille, France.
Coauthors: Akimoto, T., Takahashi, A., Celani, F.
Summary
We observed neutron emissions from pure deuterium gas after it was cooled in liquid nitrogen and placed in a magnetic field. Neutron emissions were observed in ten out of ten test cases. Neutron burst of 5.5 c/s were 1000 times higher than the background counts. These bursts occurred one or two times within a 300 second interval. The total neutron emission can be estimated from the counting efficiency, and it was 104 ~ 105 c/s. The reaction appears to be highly reproducible, reliably generating high neutron emissions. We conclude that the models proposed heretofore based upon d-d reactions are inadequate to explain the present results, which must involve magnetic field nuclear reactions.
Mizuno, T. and Y. Toriyabe. Anomalous energy generation during conventional electrolysis. in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Toriyabe, Y.We experienced an explosive energy release during a conventional electrolysis experiment. The cell was a 1000 cc Pyrex glass vessel that has been in use for 5 years. It contained 700 cc of 0.2 M K2CO3 electrolyte; a platinum mesh anode; and a tungsten cathode wire 1.5 mm in diameter, 29 cm long, with 3 cm exposed to the electrolyte. The estimated heat out was 800 times higher than input power, based on the data recorded up to the moment of the event. There were many elements deposited on the electrode surface. The major elements were Ca and S and the total mol was roughly estimated as 10-6.
Mizuno, T., et al., Hydrogen Evolution by Plasma Electrolysis in Aqueous Solution. Jpn. J. Appl. Phys. A, 2005. 44(1A): p. 396-401.
Coauthors: Akimoto, T., Azumi, K., Ohmori, T., Aoki, Y., Takahashi, A.Hydrogen has recently attracted attention as a possible solution to environmental and energy problems. If hydrogen should be considered an energy storage medium rather than a natural resource. However, free hydrogen does not exist on earth. Many techniques for obtaining hydrogen have been proposed. It can be reformulated from conventional hydrocarbon fuels, or obtained directly from water by electrolysis or high-temperature pyrolysis with a heat source such as a nuclear reactor. However, the efficiencies of these methods are low. The direct heating of water to sufficiently high temperatures for sustaining pyrolysis is very difficult. Pyrolysis occurs when the temperature exceeds 4000ºC. Thus plasma electrolysis may be a better alternative, it is not only easier to achieve than direct heating, but also appears to produce more hydrogen than ordinary electrolysis, as predicted by Faradays laws, which is indirect evidence that it produces very high temperatures. We also observed large amounts of free oxygen generated at the cathode, which is further evidence of direct decomposition, rather than electrolytic decomposition. To achieve the continuous generation of hydrogen with efficiencies exceeding Faraday efficiency, it is necessary to control the surface conditions of the electrode, plasma electrolysis temperature, current density and input voltage. The minimum input voltage required induce the plasma state depends on the density and temperature of the solution, it was estimated as 120V in this study. The lowest electrolyte temperature at which plasma forms is ~75ºC. We have observed as much as 80 times more hydrogen generated by plasma electrolysis than by conventional electrolysis at 300 V.
Mizuno, T., Jyouon kakuyuugou purojekuto (cold fusion project). 2006: LENR-CANR.
Coauthors:An e-book in Japanese reviewing the field. Describes Mizuno's own research, as well as projects at Osaka University, NTT, Iwate University, Nagoya University and the Tokyo Institute of Technology.
Mizuno, T. and S. Sawada. Anomalous Heat Generation during Hydrogenation of Carbon (Phenanthrene). in ICCF-14 International Conference on Condensed Matter Nuclear Science. 2008. Washington, DC.
Coauthors: Sawada, S.When phenanthrene (a heavy oil fraction) is subjected to high pressure and heat in a reactor with a metal catalyzer, it produces a markedly anomalous reaction. It produces excess heat and weak radiation, specifically x-rays and gamma-rays. Furthermore, after the reaction finishes, mass spectroscopy reveals what appears to be 13C. It is very difficult to explain the total energy generation as a conventional chemical reaction. After the experiment, almost all phenanthrene and hydrogen gas remains in the same condition they were initially. There are few reaction products such as other chemical compounds. However, the formation enthalpies for these compounds are all negative. The heat generation sometimes reaches 0.1 kW and has continued for several hours. There is a reasonably significant correspondence between the heat generation and the gamma emission. We have confirmed the same result with high reproducibility by controlling temperature and pressure.
Mizuno, T., Transmutation Reactions in Condensed Matter, in Low-Energy Nuclear Reactions Sourcebook. 2008, American Chemical Society: Washington, DC. p. 271-294.
Coauthors:Mizuno, T. Confirmation of Heat Generation during Hydrogenation of Oil (PowerPoint slides). in 15th International Conference on Condensed Matter Nuclear Science. 2009. Rome, Italy: ENEA.
Coauthors:
* Anomalous heat generation was confirmed during the heating of phenanthrene in high-pressure H2 gas.
* Sporadic radiation emissions (probably gamma rays) were confirmed during the high temperature experiments.
* A weak correlation was observed between the anomalous heat generation and the radiation emissions.
Mo, D.W., et al. Real Time Measurements of the Energetic Charged Particles and the Loading Ratio (D/Pd). in Third International Conference on Cold Fusion, "Frontiers of Cold Fusion". 1992. Nagoya Japan: Universal Academy Press, Inc., Tokyo, Japan.
Coauthors: Zhang, L., Chen, B. X., Liu, Y. S., Doing, S. Y., Yao, M. Y., Zhou, L. Y., Huang, H. G., Li, X. Z., Shen, X. D., Wang, S. C., Kang, T. S., Huang, N. Z.Mo, D.W., et al. The Evidence of Nuclear Transmutation Phenomeno in Pd-H System Using NAA (Neutron Activation Analysis). in The Seventh International Conference on Cold Fusion. 1998. Vancouver, Canada: ENECO, Inc., Salt Lake City, UT.
Coauthors: Cai, Q. S., Wang, L. M., Wang, S. Z.Mo, W., et al. Search for Precursor and Charged Particles in "Cold Fusion". in Second Annual Conference on Cold Fusion, "The Science of Cold Fusion". 1991. Como, Italy: Societa Italiana di Fisica, Bologna, Italy.
Coauthors: Liu, Y. S., Zhou, L. Y., Dong, S. Y., Wang, K. L., Wang, S. C., Li, X. Z.Moagar-Poladian, G. A Possible Mechanism For Cold Fusion. in 15th International Conference on Condensed Matter Nuclear Science. 2009. Rome, Italy: ENEA.
Coauthors:We describe a mechanism for cold fusion that is able to explain how two hydrogen ions may come close enough so as to fusion as well as many of the different and independent experimental observations made during years of experiments. We present the mechanism, its weak points, the way it explains the respective phenomena and suggest some experiments that may validate further the model described by us.
Moffatt, W.G., Pd-Li Phase Diagram. 1978: General Electric.
Coauthors:Moir, R.W., Application of Muon-Catalyzed Fusion in Metal Hydrides For Isotope Production. 1989: Los Alamod.
Coauthors:Moizhes, B.Y., Formation of a compact D2 molecule in interstitial sites - a possible explanation for cold nuclear fusion. Sov. Tech. Phys. Lett., 1991. 17: p. 540.
Coauthors:Montereali, R., et al. A Novel LiF-Based Detector For X-Ray Imaging In Hydrogen Loaded Ni Films Under Laser Irradiation. in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Almaviva, S., Marolo, T., Vincenti, M., Sarto, F., Sibilia, C., Castagna, E., Violante, V.A novel soft X-ray imaging film detector, based on optically stimulated luminescence of active color centers in lithium fluoride, LiF, has been used to obtain the image of radiation emitted from a nickel film hydride loaded by electrolysis, under light coupling with an He-Ne laser.
Montereali, R., et al. Lithium Fluoride X-Ray Imaging Film Detectors for Condensed Matter Nuclear Measurements (PowerPoint slides). in 15th International Conference on Condensed Matter Nuclear Science. 2009. Rome, Italy: ENEA.
Coauthors: Almaviva, S., Bonfigli, F., Castagna, E., Sarto, F., Vincenti, M., Violante, V.
Lithium Fluoride, LiF, is a radiation sensitive alkali halide material well known as dosimeter and as active medium in light-emitting devices and lasers. Point defects can be produced in LiF crystals and films by different kinds of radiation. Some of these electronic defects, known as colour centres, are optically active, with broad absorption and emission bands in the visible spectral range. Novel thin-film imaging detectors for soft X-rays, based on photoluminescence from aggregate colour centres in LiF, have been proposed and are
currently under development, successfully extending their operation also in the hard X-ray region, up to 10 keV. Recently their use was proposed and preliminarily tested to obtain
the image of radiation emitted from a nickel film hydride loaded by electrolysis, under light coupling with an He-Ne laser.
Montgomery, J.R., et al. Correlated Nuclear and Thermal Measurements in D/Pd and H/Pd Systems. in Anomalous Nuclear Effects in Deuterium/Solid Systems, "AIP Conference Proceedings 228". 1990. Brigham Young Univ., Provo, UT: American Institute of Physics, New York.
Coauthors: Jeffery, R., Amiri, F., Adams, J.Monti, R.A., Low energy nuclear reactions: Experimental evidence for the alpha extended model of the atom. J. New Energy, 1996. 1(3): p. 131.
Coauthors:Monti, R.A. Nuclear Transmutation Processes of Lead, Silver, Thorium, Uranium. in The Seventh International Conference on Cold Fusion. 1998. Vancouver, Canada: ENECO, Inc., Salt Lake City, UT.
Coauthors:Moon, D., A Cold Fusion Theory. 1993.
Coauthors:Moon, D., Addendum to "Mechanisms of a disobedient science". Infinite Energy, 1996. 1(5/6): p. 89.
Coauthors:Moon, D., Review of a cold fusion theory: Mechanisms of a disobedient science. Infinite Energy, 1999. 5(28): p. 33.
Coauthors:Moon, D. The Nucleovoltaic Cell. in Eleventh International Conference on Condensed Matter Nuclear Science. 2004. Marseille, France.
Coauthors:Described in this paper is a cold fusion device that is conceptually designed to convert the energy release, from deuteron-deuteron fusion, directly to electricity at an efficiency worthy of commercial development. The working element is an N-type semiconductor which has been coated with a thin film (a few hundred angstroms) of hydrogen-active metal, for example palladium, and which is joined to a P-type semiconductor at the PN-junction. The working element is not an electrode, as such, but an electron pump.
Moore, A., The Comportment of Palladium-Hydrogen System Toward Alternating Electric Current. Trans. Electrochem. Soc., 1939. LXXV: p. 237.
Coauthors:Moore, G.A. and D.P. Smith, The Occlusion and Diffusion of Hydrogen in Metals. A. Metallographic Study of Nickel-Hydrogen. Trans. Electrochem. Soc., 1937. LXXI: p. 545.
Coauthors: Smith, D. P.Morgan, J.D., Comment on: Deuterium nuclear fusion at room temperature: a pertinent inequality on barrier penetration. J. Chem. Phys., 1990. 93: p. 6115.
Coauthors:Morgan, J.D. and H.J. Monkhurst, Simple model for accurate calculation of Coulomb-barrier penetration factors in molecular fusion rates. Phys. Rev. A: At. Mol. Opt. Phys., 1990. 42(9): p. 5175.
Coauthors: Monkhurst, H. J.Morioka, S., Nuclear fusion triggered by positron annihilation at vacancies in deuterated metals. Nuovo Cimento Soc. Ital. Fis. A, 1994. 107A: p. 2755.
Coauthors:Morrey, J.R., et al., Measurements of helium in electrolyzed palladium. Fusion Technol., 1990. 18: p. 659.
Coauthors: Caffee, M. W., Farrar IV, H., Hoffman, N. J., Hudson, G. B., Jones, R. H., Kurz, M. D., Lupton, J., Oliver, B. M., Ruiz, B. V., Wacker, J. F., van Veen, A.Morrison, D.R.O., A view from CERN. Physics World, 1989. 2: p. 17.
Coauthors:Morrison, D.R.O. Review of Cold Fusion. in 8th World Hydrogen Energy Conf. 1990. Honolulu, HI: Hawaii Natural Energy Institute, 2540 Dole St., Holmes Hall 246, Honolulu, HI 96822.
Coauthors:Morrison, D.R.O., The Rise And Decline of Cold Fusion. Physics World, 1990: p. 35.
Coauthors:Morrison, D.R.O., Review of cold fusion. Sov. Phys. Usp., 1991. 34: p. 1055.
Coauthors:Morrison, D.R.O., Comments on claims of excess enthalpy by Fleischmann and Pons using simple cells made to boil. Phys. Lett. A, 1994. 185: p. 498.
Coauthors:Morrison, D.R.O., Review of Progress in Cold Fusion. Trans. Fusion Technol., 1994. 26(4T): p. 48.
Coauthors:Mosier-Boss, P.A. and S. Szpak, The Metal Hydrogen System: Interphase Participation in H-Transport. 1995, Naval Control, Command and Ocean Surveillance Center, RDT&E Division.
Coauthors: Szpak, S.
This paper is available as a single file (below), and it is included in:
Szpak, S. and P.A. Mosier-Boss, Anomalous Behavior of the Pd/D System. 1995, Office of Naval Research.
ABSTRACT
The metal/hydrogen system is a key element in the construction of ecologically preferred energy conversion/storage devices. Although reduced to practice decades ago, its effectiveness requires further examination of a number of issues, among them the role that the electrode/electrolyte interphase plays during the charging/discharging processes. In this communication the following topics are considered: Thermodynamics and kinetics of the structure of the interphase, the identity and components of the driving force(s) for the absorption/desorption of hydrogen, and the discussion of the applicable transport equation. Agreement between theoretical results and observed behavior is illustrated and selected design approaches affecting cell performance are explored.
Mosier-Boss, P.A. and S. Szpak, The Pd/(n)H system: transport processes and development of thermal instabilities. Nuovo Cimento Soc. Ital. Fis. A, 1999. 112: p. 577.
Coauthors: Szpak, S.Summary. -- Surface temperature distribution associated with excess enthalpy production during the codeposition process is presented. The interpretation is sought via the multilayer concept of the electrode/electrolyte interphase. The effect of gas evolution on activities within the interphase is considered.
Mosier-Boss, P.A., et al., Thermal and Nuclear Aspects of the Pd/D2O System (1), ed. S. Szpak and P.A. Mosier-Boss. Vol. 1 A Decade of Research at Navy Laboratories. 2002: SPAWAR Systems Center, San Diego, U.S. Navy.
Coauthors: Chubb, S. R., Fleischmann, M., Imam, M. A., Miles, M., Szpak, S.
Twelve years have passed since the announcement on 23 March 1989 by professors Fleischmann and Pons that the generation of excess enthalpy occurs in electrochemical cells when palladium electrodes, immersed in D2O + LiOH electrolyte, are negatively polarized. The announcement, which came to be known as Cold Fusion, caused frenzied excitement. In both the scientific and news communities, fax machines were used to pass along fragments of rumor and facts. (Yes, this was before wide spread use of the internet. One can only imagine what would happen now.) Companies and individuals rushed to file patents on yet to be proven ideas in hopes of winning the grand prize. Unfortunately, the phenomenon described by Fleischmann and Pons was far from being understood and even factors necessary for repeatability of the experiments were unknown. Over the next few months, the scientific community became divided into the believers and the skeptics. The believers reported the results of their work with enthusiasm that at times overstated the significance of their results. On the other hand, many skeptics rejected the anomalous behavior of the polarized Pd/D system as a matter of conviction, i.e., without analyzing the presented material and always asking where are the neutrons? Funding for research quickly dried up as anything related to Cold Fusion was portrayed as a hoax and not worthy of funding. The term Cold Fusion took on a new definition much as the Ford Edsel had done years earlier.
Dr. Frank E. Gordon, Head, Navigation and Applied Sciences Department, Space and Naval Warfare Systems Center, San Diego
Mosier-Boss, P.A. and M. Fleischmann, Thermal and Nuclear Aspects of the Pd/D2O System (2), ed. S. Szpak and P.A. Mosier-Boss. Vol. 2. Simulation of the Electrochemical Cell (ICARUS) Calorimetry. 2002: SPAWAR Systems Center, San Diego, U.S. Navy.
Coauthors: Fleischmann, M.
FOREWORD
The calorimetry of any electrochemical cell involves two types of activities: data collection and data evaluation. The required data are the cell potentialtime and cell temperaturetime series. The evaluation is based on conservation laws subject to constraints dictated by cell design and the adapted experimental procedure. Volume 2 of this report deals with the modeling and simulation of the Dewar-type calorimeter. It was written by Professor Fleischmann to provide an authoritative discussion of the calorimetry of electrochemical cells. The emphasis is on the interpretation of data and the accuracy of the determination of the excess enthalpy generation via the appropriate selection of heat transfer coefficients. The discussion of the calorimetry of the Dewar-type cells is presented in the form of technical report for a number of reasons,
among them: (i) its length would likely prohibit publication in topical journals, (ii) to clarify misunderstandings regarding the principles of calorimetry as applied to electrochemical cell in general and to the cell employed by Fleischmann and his collaborators, in particular.
S. Szpak and P.A. MosierBoss, eds.
Mosier-Boss, P.A., et al. Pd/D Co-Deposition: Excess Power Generation and Its Origin (paper and PowerPoint slides). in 233rd ACS National Meeting. 2007. Chicago, IL.
Coauthors: Szpak, S., Gordon, F., Forsley, L., Phillips, G.
Early Pd/D co-deposition experiments demonstrated excess enthalpy, formation of hot spots, emission of low intensity radiation, and production of tritium.
Excess enthalpy is generated by highly energetic fast reactions that resemble mini-explosions. This view is supported by IR imaging (hot spots) and by the response of the pressure/temperature sensitive substrates (piezoelectric material) onto which the Pd/D films are co-deposited.
An external electric/magnetic field changes the shape of the individual globules of the cauliflower structure of the Pd/D co-deposited material.
New elements are observed that are associated with the morphological features formed by the action of the external E/B fields.
Using CR-39 detectors, tracks are obtained that are consistent with both nuclear charged particles and neutron knock-on tracks.
Mosier-Boss, P.A., S. Szpak, and F. Gordon. Production of High Energy Particles Using the Pd/D Co-Deposition Process (PowerPoint slides). in APS March Meeting. 2007. Denver, CO.
Coauthors: Szpak, S., Gordon, F.PowerPoint slides from the American Physical Society March 2007 conference.
Mosier-Boss, P.A., et al., Use of CR-39 in Pd/D co-deposition experiments. Eur. Phys. J. Appl. Phys., 2007. 40: p. 293-303.
Coauthors: Szpak, S., Gordon, F., Forsley, L.The use of CR-39, a solid state nuclear track detector, to detect the emission of energetic charged particles during Pd/D co-deposition is demonstrated. The pits observed in the CR-39 are attributed to the Pd/D cathode and are not due to radionuclide contamination in the cell components; nor to the impingement of D2 bubbles on the surface of the CR-39; nor to chemical attack by D2, O2, or Cl2. The features (i.e., optical contrast, shape, and bright spot in the center of the pit) of the pits generated during Pd/D co-deposition are consistent with those observed for pits that are of a nuclear origin.
Mosier-Boss, P.A., et al., Detection of Energetic Particles and Neutrons Emitted During Pd/D Co-Deposition, in Low-Energy Nuclear Reactions Sourcebook. 2008, American Chemical Society: Washington, DC. p. 311-334.
Coauthors: Szpak, S., Gordon, F., Forsley, L.Mosier-Boss, P.A., et al., Reply to Comment on 'The Use of CR-39 in Pd/D Co-deposition Experiments': A Response to Kowalski. Eur. Phys. J. Appl. Phys., 2008. 44: p. 287-290.
Coauthors: Szpak, S., Gordon, F., Forsley, L.Earlier we reported, in this journal, that the pits generated in CR-39 detectors during Pd/D co-deposition experiments are consistent with those observed for pits that are of a nuclear origin. Recently, that interpretation has been challenged. In this communication, additional experimental data and further analysis of our earlier results are provided that support our original conclusions.
Mosier-Boss, P.A., et al., Triple tracks in CR-39 as the result of PdâD Co-deposition: evidence of energetic neutrons. Naturwiss., 2008. doi:10.1007/s00114-008-0449-x(96): p. 135-142.
Coauthors: Szpak, S., Gordon, F., Forsley, L.Mosier-Boss, P.A., F. Gordon, and L. Forsley, Characterization of Energetic Particles Emitted During Pd/D Co-Deposition for Use in a Radioisotope Thermoelectric Generator (RTG), in Low-Energy Nuclear Reactions and New Energy Technologies Sourcebook Volume 2. 2009, American Chemical Society: Washington DC. p. 119-135.
Coauthors: Gordon, F., Forsley, L.Mosier-Boss, P.A., et al., Characterization of tracks in CR-39 detectors obtained as a result of Pd/D Co-deposition. Eur. Phys. J. Appl. Phys., 2009. 46.
Coauthors: Szpak, S., Gordon, F., Forsley, L.Earlier we reported that the pits generated in CR-39 detectors during Pd/D co-deposition experiments are consistent with those observed for pits that are of a nuclear origin. Spacer experiments and track modeling have been done to characterize the properties of the particles that generated the tracks in the CR-39 detectors. The effect of water on the energetics of the particles and their resultant tracks is discussed.
Mosier-Boss, P.A., et al., Comparison of Pd/D co-deposition and DT neutron generated triple tracks observed in CR-39 detectors. Eur. Phys. J. Appl. Phys., 2010. 51.
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Coauthors: Besenbacher, F.Muromtsev, V., V. Platonov, and I. Savvatimova. Neutrino-Dineutron Reactions (Low-Energy Nuclear Reactions Induced By D2 Gas Permeation Through Pd Complexes. Y. Iwamura Effect). in The 12th International Conference on Condensed Matter Nuclear Science. 2005. Yokohama, Japan.
Coauthors: Platonov, V., Savvatimova, I.Anomalous elemental changes have been observed on the Pd complexes after D2 gas permeation. This effect -- effect Y. Iwamura -- belongs to a new category of nuclear reactions. The effect of Y. Iwamura can stimulate development of physics of electromagnetic interaction neutrino including physics of relic neutrino and physics of the dineutrons. It is possible to suggest that low-energy neutrino and even relic neutrino can initiate effect of transmutation in special cases. The suggested hypothesis application about new class ν− nuclear reaction existence can be useful for the problems: alternative energetic, radioactive isotopes reducing and rare isotopes production.
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Coauthors: Iyengar, T. S., Sen, B. K., Joseph, T. B.
The report summarises the methodology and techniques adopted for the determination of tritium content in various samples obtained during the initial sets of experiments conducted at Trombay in connection with studies on the feasibility of Cold Fusion.
The analyses were carried out at the Isotope Division and Health Physics Division.
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Coauthors: Richards, P. M., Follstaedt, D. M., Schirber, J. E.Nace, D.M. and J.G. Aston, Palladium Hydride. I. The Thermodynamic Properties of Pd2H Between 273 and 345 K. J. Am. Chem. Soc., 1957. 79: p. 3619.
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Coauthors: Aston, J. G.Nace, D.M. and J.G. Aston, Palladium Hydride. III. The Thermodynamic Study of Pd2H Between 15 and 303Ã K. Evidence for the Tetragonal PdH4 Structure in Palladium Hydride. J. Am. Chem. Soc., 1957. 79: p. 3627.
Coauthors: Aston, J. G.